Controlling moving interfaces in solid-state batteries
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Abstract
All-solid-state lithium metal batteries enable high-energy-density applications, such as electric aviation, but suffer from instabilities during operation that lead to rough interfaces between the metal and electrolyte. These cause void formation and dendrite growth that degrades performance and safety. Inspired by the morphogenetic control of thin lamina such as tree leaves that robustly grow into flat shapes, we propose a range of approaches to control lithium metal stripping and plating via a range of feedback mechanisms. A minimal model that captures the coupling between interface motion, thermodynamics, electrochemistry and mechanics shows that local feedback cannot stop the formation of rough interfaces, while long-range feedback allows us to stabilize the interface and keep it flat. Our theoretical study suggests various approaches to achieve this, and provides the beginning of a practical framework for …




Prof. L. Mahadevan

